TREATMENT of FEROUS MATERIALS


Iron is the major constituent in the steel used in tooling, to which carbon is added in order that the steel may harden. Alloys are put into steel to enable it to develop properties not possessed by plain carbon steel, such as ability to harden in oil or air, increased wear resistance, higher toughness, and greater safety in hardening.
Heat treatment of ferrous materials involves several important operations which are customarily to under various headings, such as normalizing, spheroidizing, stress relieving, annealing, hardening, tempering, and case hardening.

Normalizing
This is the operation of heating to temperature about 100F to 200F  above the critical range a cooling in still air. This is about 100F over the regular hardening temperature. The purpose of normalizing is usually to refine grain structure that have been coarsened in forging. With most of the medium carbon forging steels, alloyed and unalloyed, normalizing is highly recommended after forging and before machining to produce more homogeneous structures and in most cases improved machinability.
High alloy air hardening steels are never normalized, since to do so would them to harden and defeat the primary purpose.

Spheroidizing
This is a form of annealing which, in the process of heating and cooling steel, produces a rounded or globular form of carbide the hard constituent in steel.
Tool steel are normally spherodized for best machinability. This is accomplished by heating to a temperature of 1380-1400F for carbon steels and higher for many alloy tool steels, holding at heat one to four hours, and cooling slowly in the furnace.

Stress Relieving
This is a method of relieving the internal stresses set up in steel during forming, cold working, and cooling after welding or machining. It is the most simple heat treatment and is accomplished by merely  heating to 1200-1350F followed by air or furnace cooling.
Large dies are usually roughed out, then stress relieved and finish machined. This will minimize change of shape not only during machining but during subsequent heat treating as well. Welded sections will also have locked in stress owing to a combination of differential heating and cooling cycle as well as to changes in cross section. Such stresses will cause considerable movement in machining operations.

Annealing
The process of annealing consist  of heating the stell to an elevated temperature for a definite period of time and, usually, cooling it slowly. Annealing is done to produce homogenization and to establish normal equilibrium conditions, with corresponding characteristic properties.
Tool steel as purchased is generally in the annealed condition. Sometimes it is necessary to rework a tool that has been hardened, and the tool must then be annealed. For this type  of anneal, the steel is heated slightly above its critical range and than cooled very slowly.
Finished parts may be annealed without surface deterioration by placing them in a closed pot and covering with compounds that will combine with the air present to form a reducing atmosphere. Partially spent carburizing compound is widely used, as well as cast iron chips, charcoal, and commercial neutral compounds.

Hardening
This is the process of heating to a temperature above the critical range, and cooling rapidly enough through the critical range to appreciably harden the steel.
A simplified theory of hardening steel is that iron has two distinct  and different atomic arrangements, one existing at room temperature or gain near the melting point, and one above the critical temperature. Without this phenomenon it would be impossible to harden iron base alloys by heatreatment.

Tempering
This is the process of heating quenched and hardened steel and alloy to some temperature below the lower critical temperature to reduce internal stresses set up in hardening. Thus the hard martensite resulting from the quenching operation is changed in tempering in the direction of the equilibrium properties, the degree being dependent on the tempering temperature and rate of cooling.

Case Hardening
The addition of carbon to the surface of steel parts and subsequent hardening operation are important phase in heat treating. The process may involve the use of molten sodium cyanide mixtures, pack carburizing with activated solid material, such as charcoal, or coke, gas, or oil carburizing, and dry cyaniding.
Whether a solid carbonaceous packing material is used, or a liquid gas, the objective is to produce a hard, wear resistant surface with a core of such hardness or toughness as is best suited for the purpose. The carbon content of the surface is raised to 0.80-1.20% and the case depth can be closely controlled by the time, the temperature, and the carburizing medium used. Pack carburizing is generally done at 1700F for eight hours to produce a case depth of 1/16 in, Light cases up to 0.005in. can be obtained in liquid cyanide baths and case depths to 1/32in. are economically practical in liquid carburizing baths.
Usually low carbon and low carbon alloy steel are carburized. The usual carbon range is 0.10 to 0.30% carbon, though higher carbon content steel may be carburized as well.

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